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排序方式: 共有486条查询结果,搜索用时 31 毫秒
31.
Paula Paíga Lúcia H. M. L. M. Santos Célia G. Amorim Alberto N. Araújo M. Conceição B. S. M. Montenegro Angelina Pena Cristina Delerue-Matos 《Environmental science and pollution research international》2013,20(4):2410-2420
Ibuprofen is amongst the most worldwide consumed pharmaceuticals. The present work presents the first data in the occurrence of ibuprofen in Portuguese surface waters, focusing in the north area of the country, which is one of the most densely populated areas of Portugal. Analysis of ibuprofen is based on pre-concentration of the analyte with solid phase extraction and subsequent determination with liquid chromatography coupled to fluorescence detection. A total of 42 water samples, including surface waters, landfill leachates, Wastewater Treatment Plant (WWTP), and hospital effluents, were analyzed in order to evaluate the occurrence of ibuprofen in the north of Portugal. In general, the highest concentrations were found in the river mouths and in the estuarine zone. The maximum concentrations found were 48,720 ng?L?1 in the landfill leachate, 3,868 ng?L?1 in hospital effluent, 616 ng?L?1 in WWTP effluent, and 723 ng?L?1 in surface waters (Lima river). Environmental risk assessment was evaluated and at the measured concentrations only landfill leachates reveal potential ecotoxicological risk for aquatic organisms. Owing to a high consumption rate of ibuprofen among Portuguese population, as prescribed and non-prescribed medicine, the importance of hospitals, WWTPs, and landfills as sources of entrance of pharmaceuticals in the environment was pointed out. Landfill leachates showed the highest contribution for ibuprofen mass loading into surface waters. On the basis of our findings, more studies are needed as an attempt to assess more vulnerable areas. 相似文献
32.
Régia Maria Avancini Iandara Schettert Silva Ana Cristina Simões Rosa Paula de Novaes Sarcinelli Sueli Alexandra de Mesquita 《Chemosphere》2013,90(9):2408-2413
Organochlorines are highly hydrophobic, synthetic organic pollutants that accumulate in the environment and in food webs. The primary route of human exposure to organochlorines is through food-mainly fat-rich food of animal origin such as meat, fish, and dairy products. Here we determined the presence and concentration of organochlorine residues in pasteurized milk from Mato Grosso do Sul, Brazil, to monitor consumer exposure to these contaminants. Organochlorine pesticides in milk samples were analyzed using solid phase extraction in octadecyl silica-prepacked columns and identified by gas chromatography using an electron capture detector. Of the 100 composite samples analyzed, more than 90% contained residues of organochlorine pesticides: aldrin was present in 44% of the samples, followed by ∑DDT (36%), mirex (34%), endosulfan (32%), chlordane (17%), dicofol (14%), heptachlor (11%) and dieldrin (11%). Compared to the values established by law, the concentration of the compounds in some samples was above the reference values. Given the importance that milk and its products have in the human diet, it is essential to know whether the levels of pesticide residues are kept well below the recommended levels to minimize the risk to human health. 相似文献
33.
This study modeled the impact on freshwater ecosystems of pharmaceuticals detected in biosolids following application on agricultural soils. The detected sulfonamides and hydrochlorothiazide displayed comparatively moderate retention in solid matrices and, therefore, higher transfer fractions from biosolids to the freshwater compartment. However, the residence times of these pharmaceuticals in freshwater were estimated to be short due to abiotic degradation processes. The non-steroidal anti-inflammatory mefenamic acid had the highest environmental impact on aquatic ecosystems and warrants further investigation. The estimation of the solid-water partitioning coefficient was generally the most influential parameter of the probabilistic comparative impact assessment. These results and the modeling approach used in this study serve to prioritize pharmaceuticals in the research effort to assess the risks and the environmental impacts on aquatic biota of these emerging pollutants. 相似文献
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Francesca R. Grati Francesca Malvestiti Beatrice Grimi Elisa Gaetani Anna Maria Di Meco Anna Trotta Rosaria Liuti Sara Chinetti Francesca Dulcetti Anna Maria Ruggeri Cristina Agrati Giuditta Frascoli Silvia Milani Simona De Toffol Lorenza Martinoni Silvia Paganini Livia Marcato Federico Maggi Giuseppe Simoni 《黑龙江环境通报》2013,33(5):502-508
38.
Moretto Cristiane Castellane Tereza Cristina Luque Leonel Tatiane Fernanda Campanharo Joao Carlos de Macedo Lemos Eliana Gertrudes 《Environmental science and pollution research international》2022,29(31):46953-46967
Environmental Science and Pollution Research - Rhizosphere bacteria, for example, rhizobia, can play several roles, and one of the most important, the protection of plant roots against toxic... 相似文献
39.
Monje Dany Santiago Ruiz Orlando Simón Valencia Gloria Cristina Mercado D. Fabio 《Environmental science and pollution research international》2022,29(38):57127-57146
Environmental Science and Pollution Research - Seven composites of iron oxide nanoparticles embedded in organic microparticles mediated by Cu(II) were synthesized using yerba mate (Ilex... 相似文献
40.
Errazquin Diego Mohamadou Aminou Dupont Laurent De Gaetano Yannick García Cristina B. Lomba Laura Giner Beatriz 《Environmental science and pollution research international》2021,28(46):65374-65384
Environmental Science and Pollution Research - This work studies the effects of different bromide-based ionic liquids, with phosphonium and ammonium cations, towards several environmental... 相似文献